The contents of the DVDs are as follows:
Disc 1: "The Man Trap," "Charlie X," "Where No Man Has Gone Before,"* "The Naked Time"
Disc 2: "The Enemy Within," "Mudd's Women," "What Are Little Girls Made Of?" "Miri"
Disc 3: "Dagger of the Mind," "The Corbomite Maneuver," "The Menagerie, Part I,"* The Menagerie, Part II"*
Disc 4: "The Conscience of the King,"* "Balance of Terror," "Shore Leave," "The Galileo Seven"
Disc 5: "The Squire of Gothos," "Arena," "Tomorrow is Yesterday," "Court Martial"
Disc 6: "The Return of the Archons," "Space Seed," "A Taste of Armageddon," "This Side of Paradise"
Disc 7: "The Devil in the Dark," "Errand of Mercy," "The Alternative Factor," "The City on the Edge of Forever"
Disc 8: "Operation: Annihilate!"
* These four episodes have text commentary by Michael Okuda and Denise Okuda


Disc 8 Features:
• The Birth of a Timeless Legacy
• Life Beyond Trek: William Shatner
• To Boldly Go...
• Reflections on Spock
• Sci-Fi Visionaries
• Original Preview Trailers
• Photo Log