You must have really wanted to add Desperado because you have it twice in your honorable mention list. ;)

Seriously, though, I have to give you props because of your final two. I would have reversed them (Cary Grant is the sexiest movie star of all time, all time I say! :) ) but how can I complain when I actually agree with you for once? It's fairly odd, I must say.

I would have had Casablanca on the list, as well as Romeo & Juliet, but overall this is nicely done. And you simply cannot go wrong with Newman, Taylor, Grant and Kelly. You just can't!

(I probably would have added Harrison Ford and Kelly McGillis, too, for Witness. Their scenes together are just downright electric!)

1) Rick Blaine and Ilsa Lund "Casablanca"
2) Remy & Ann "The Big Easy"
3) Noah & Allie "The Notebook" (best kiss too)
4) Elizabeth Bennett & Mr. Darcy "Pride and Prejudice"
5) Violet & Corky "Bound"
6) Ennis & Jack "Brokeback Mountain" (Runner up for best kiss)
7) Jim & Claudie "Magnolia"
8) Jack & Rose "Titanic"
9) Wesley and Buttercup "The Princess Bride"
10) Sam & Molly "Ghost"

I would have had Casablanca on the list, as well as Romeo & Juliet, but overall this is nicely done.

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So, I just came across this "Top Ten" list and decided I have to add my own:

My Top Ten picks:
1. Brad Pitt and Angelina Jolie in Mr and Mrs Smith
2. Paul Newman and Elizabeth Taylor in Cat on a Hot Tin Roof
3. Cary Grant and Sophia Loren in Houseboat
4. Clark Gable and Vivien Leigh in Gone With the Wind
5. Harrison Ford and Anne Heche in Six Days Seven Nights
6. Kevin Costner and Madeline Stowe in Revenge
7. Mel Gibson and Michelle Pfeiffer in Tequila Sunrise
8. Keanu Reeves and Aitana Sanchez-Gijon in A Walk in the Clouds
9. Laura Harring and Naomi Watts in Mulholland Drive
10. Hugh Jackman and Meg Ryan in Kate and Leopold

My honorable mentions…
11. Sean Connery and Catherine Zeta-Jones in Entrapment
12. John Wayne and Maureen O'Hara in McLintock!
13. John Travolta and Kyra Sedgwick in Phenomenon
14. Michael Douglas and Kathleen Turner in Romancing the Stone
15. Tom Cruise and Kelly McGillis in Top Gun
16. Leonardo DiCaprio and Kate Winslet in Titanic
17. Heath Ledger and Jake Gyllenhaal in Brokeback Mountain
18. Olivier Martinez and Diane Lane in Unfaithful
19. Bruce Willis and Jessica Alba in Sin City
20. Brendan Fraser and Rachel Wiesz in The Mummy

Just to name a few…

Diane Lane and Olivier Martinez (Unfaithful)

Angelina Jolie and Brad Pitt (Mr and Mrs Smith)

Rachel McAdams and Ryan Gosling (The Notebook)

Sarah Jessica Parker and Chris Noth (Sex and the City)

michael cera and kat dennings ( nick and norah's infinite playlist)
heath ledger and jake gyllenhaal ( brokeback mountain)
josh hartnett and kate beckinsale ( pearl harbour)
shane west and mandy moore ( a walk to remember)
ryan gosling and rachel mcadams (the notebook)
ewan mcgregor and nicole kidman (moulin rouge)
brad pitt and rose bryne (troy)

ummmm….what about catherine zeta-jones & antonio banderas in the mask of zorro??? come on, that sword fight/ strip/ kiss scene was HOT!!! and i'm not just talking about both of them…